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Write the chemical formula of the dibromobis(oxalato)cobaltate(III)ion.

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Predict the number of unpaired electrons in the [CrCl6]4- ion.

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4

Bidentate and polydentate ligands are also called chelating agents.

A) True
B) False

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In the complex ion [ML6]n+, Mn+ has six d electrons and L is a weak field ligand.According to crystal field theory, the magnetic properties of the complex ion correspond to how many unpaired electrons?


A) 0
B) 1
C) 2
D) 3
E) 4

F) C) and D)
G) B) and D)

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In the following pair of complex ions, choose the one that absorbs light at a longer wavelength.


A) [Co(H2O) 6]2+ In the following pair of complex ions, choose the one that absorbs light at a longer wavelength.  A) [Co(H<sub>2</sub>O) <sub>6</sub>]<sup>2+</sup>    B) [Co(NH<sub>3</sub>) <sub>6</sub>]<sup>2+</sup>
B) [Co(NH3) 6]2+

C) A) and B)
D) undefined

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A

In the coordination compound [Cr(NH3) (en) 2Cl]Br2, the coordination number (C.N.) and oxidation number (O.N.) of the metal atom are, respectively,


A) C.N.= 6; O.N.= +4.
B) C.N.= 6; O.N.= +3.
C) C.N.= 5; O.N.= +2.
D) C.N.= 4; O.N.= +2.
E) C.N.= 4; O.N.= +3.

F) A) and C)
G) C) and D)

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The correct formula for the dibromobis(oxalato)cobaltate(III)ion is [Co(C2O4)Br2]3+.

A) True
B) False

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Labile complexes are coordination complexes that


A) are labeled with a radioactive isotope.
B) are thermodynamically stable.
C) are thermodynamically unstable.
D) undergo rapid ligand exchange reactions.
E) undergo very slow ligand exchange reactions.

F) C) and D)
G) B) and D)

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The numbers of geometrical isomers and optical isomers of the complex ion [Co(en) 3]3+ are, respectively,


A) 2 and 2.
B) 1 and 1.
C) 3 and 2.
D) 1 and 2.
E) 2 and 4.

F) B) and D)
G) A) and B)

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Draw and label the geometric isomers of [CrF2Cl4]3-?

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11ea7cc5_01cc_ed11_a2ab_f749cc0de8c5_TB3245_00

In the complex ion [ML6]n+, Mn+ has seven d electrons and L is a weak field ligand.According to crystal field theory, the magnetic properties of the complex ion correspond to how many unpaired electrons?


A) 0
B) 1
C) 2
D) 3
E) 5

F) C) and D)
G) A) and C)

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The electron configuration of a Co3+ ion is


A) [Ar]3d6.
B) [Ar]4s13d5.
C) [Ar] 4s23d4.
D) [Ar]3d5.
E) [Ar]3d4.

F) B) and D)
G) B) and C)

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In the coordination compound [Co(en) 2Cl2]Cl, the coordination number and oxidation number of the central atom are, respectively,


A) 4, +3.
B) 6, +2.
C) 4, +2.
D) 6, +3.
E) 4, +1.

F) C) and D)
G) A) and C)

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Write the chemical formula of diamminedichloroplatinum(II).

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Name the complex ion [CuCl3Br(NH3)2]2-.

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diamminebr...

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Predict the number of unpaired electrons in the [Cr(en)3]2+ ion.

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The ion [Co(NH3) 6]2+ is octahedral and high spin. This complex is


A) paramagnetic, with 1 unpaired electron.
B) paramagnetic, with 3 unpaired electrons.
C) paramagnetic, with 4 unpaired electrons.
D) paramagnetic, with 5 unpaired electrons.
E) diamagnetic.

F) A) and B)
G) A) and C)

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The best name for K4[FeCl2(CN) 4] is


A) tetrapotassium dichlorodicyanoiron(II) .
B) potassium dichlorodicyanoiron(II) .
C) potassium dichlorodicyanoferrate(III) .
D) tetrapotassium dichlorobis(cyano) iron(III) .
E) potassium dichlorotetracyanoferrate(II) .

F) A) and E)
G) C) and D)

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The total number of electrons in the 3d orbitals of Ti3+ is


A) 0
B) 1
C) 2
D) 3
E) 4

F) A) and C)
G) B) and C)

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Predict the number of unpaired electrons in the [Fe(CN)6]3- ion.

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